Fire Behavior & Combustion

Author(s): Michael McKenna

Edition: 1

Copyright: 2022

Edition: 2

Copyright: 2024

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The audience for the book is primarily members of the fire service studying fire as part of a degree program, as well as anyone wanting to study fire. The intent of the book is to provide a depth of knowledge in fi re behavior, so hopefully, to provide just a bit of fire behavior information that will help firefighters make more informed decisions. It is also intended to provide enough science and extra physics, so hopefully, as the National Institute for Standards and Technology and the Fire Safety Research Institute continue to study fire, understanding the information will come more naturally to the firefighter. The book is aimed as a bridge between the oversimplistic studies of fire behavior and the full-on calculus-based, deep physics textbooks. I leave mathematical calculations intentionally out of the book but put many formulas into the book to help understand the relationships between values. I attempted to leave openings where the instructor could use the text as a launching point to go into more complicated directions if they choose. I am not a scientist but have learned the value of science and mathematics by studying fire behavior. With the exception of my time in the Safety Division, I spent my entire career riding a fire engine, putting “wet stuff on the red stuff.” The book contains many case studies because I believe it is best to intertwine real events with the study of fire behavior. Unfortunately, all the case studies have one thing in common, and that is line of duty death. Fire behavior makes every fireground a dynamic and dangerous place that can be very unpredictable. What seems completely benign can become deadly in moments. I am not talking about minutes or even seconds. Sometimes tragedy happens in an instant. Case studies provide real-life fire behavior situations. It is important to note that the event in a case study does not necessarily correspond to the chapter topic. I felt that was too limiting, and there are many important circumstances to study. These fires are presented with the mindset of fire behavior, and I made no judgments or comments on any fireground actions. The presentations are about the fire behavior. This book is not perfect, and I am always open to feedback. In the process of simplification of some of the principles, I may have lost something in the translation. Hopefully, the book leads to a better understanding of the science behind fire behavior and helps forge a better understanding of fire.

Introduction 
Preface 
Cancer 
Acknowledgements 
About the author 
Fire and Emergency Services Higher Learning (FESHE) Matrix 

Chapter 1 Introduction to Fire 
1 Introduction 
1.1 The Modern Study of Fire 
1.2 National Institute of Standards and Technology (NIST) 
1.3 UL Fire Safety Research Institute (FRSI) 
1.4 Mathematics in Fire Behavior
       1.4.1 Standard International (SI) system 
       1.4.2 Scientific Notation 
       1.4.3 Temperature Measurement 
1.5 Mathematics of Change 
       1.5.1 Inverse Relationships 
       1.5.2 Rise over Run 

Chapter 2 Science of Fire 
2  Introduction 
2.1 Fire and Combustion 
       2.1.1 The Basics of Fire 
2.2 Definition of Fire 
2.3 Heat Movement 
2.4 Fire Triangle – The Initiation of Fire 
2.5 Fire Tetrahedron 
2.6 States of Energy 
       2.6.1 Potential Energy 
       2.6.2 Kinetic Energy 
2.7 Law of Conservation of Energy 
2.8 States of Matter 
       2.8.1 Gas Molecules 
              2.8.1.1 Ideal Gas Law 
       2.8.2 Liquids 
       2.8.3 Solids 

Chapter 3 Forms of Fire 
3 Introduction 
3.1 Heat Transfer Within the Reaction Zone 
       3.1.1 Second Law of Thermodynamics 
3.2 Fuel Vapor Movement Within the Reaction Zone 
       3.2.1 Fick’s Law of Diffusion 
       3.2.2 Graham’s Law of Diffusion 
3.3 Trilogy of Energy Transfer 
3.4 Pyrolysis 
3.5 Heat of Gasification 
3.6 Fire Zone 
3.7 Forms of Fire 
       3.7.1 Diffusion Flames 
              3.7.1.1 Laminar Diffusion Flame 
              3.7.1.2 Turbulent Diffusion Flame 
       3.7.2 Smoldering 
       3.7.3 Spontaneous Combustion 
              3.7.3.1 One Meridian Plaza 
       3.7.4 Premixed Flames 
              3.7.4.1 Flash Point 
              3.7.4.2 Fire Point
              3.7.4.3 Auto-Ignition Temperature 

Chapter 4 Conduction and Convection 
4 Introduction 
4.1 Heat Versus Temperature 
4.2 Conduction 
       4.2.1 Fourier’s Law of Conduction 
       4.2.2 Specific Heat 
       4.2.3 Thermal Diffusivity 
       4.2.4 Thermal Penetration Time 
4.3 Convection  
       4.3.1 Convective Heat Transfer Coefficient 
4.4 Energy Loss 

Chapter 5 Radiation 
5 Introduction 
5.1 Radiant Heat as Driving Force 
5.2 Heat Flux 
       5.2.1 Stephan-Boltzmann Constant
5.3 Emissivity 
5.4 Radiant Heat Transfer Model
5.5 Protection from Radiant Heat

Chapter 6 Ignition 
6 Introduction 
6.1 Types of Ignitions 
6.2 Ignition of Liquids 
6.3 Ignition of Solids 
       6.3.1 Surface to Mass Ratio 
       6.3.2 Net Heat Flux 
       6.3.3 Heat Flow Through a Solid 
              6.3.3.1 Steady Flow 
              6.3.3.2 Unsteady Flow 
6.4 Fire Spread 
6.5 Flame Spread 
6.6 Flame Spread on Solid Surfaces 

Chapter 7 Heat Release Rate 
7 Introduction 
7.1 Heat Release Rate 
7.2 Traditional Heat Release Rate Curve 
7.3 Legacy Versus Modern Fire Growth Curves 
       7.3.1 Modern Fire Growth Curve 
       7.3.2 t2 Fire Growth Curves 

Chapter 8 Fire Plumes and Flow Path 
8 Introduction 
8.1 Fire Plumes 
8.2 Mathematical Shape of the Fire Plume 
8.3 Buoyancy 
8.4 Entrained Air 
       8.4.1 Flame Height 
8.5 Laminar Flow 
8.6 Ceiling Jet 
8.7 Flow Path 

Chapter 9 Compartment Fires 
9 Introduction 
9.1 Compartment Fire 
       9.1.1 Stages of a Compartment Fire 
9.2 Fire Growth Timeline 
9.3 Ventilation 
9.4 Developing Fire 
9.5 Two-Zone Model
9.6 Energy Balance 

Chapter 10 Compartment Fire Dynamics 
10 Introduction 
10.1 Rollover 
10.2 Flashover 
       10.2.1 Elements of the Flashover 
       10.2.2 Conditions Required for a Flashover 
       10.2.3 Flashover Sequence of Events 
       10.2.4 Flashover Variables 
10.3 Backdraft 
       10.3.1 Backdraft Sequence 
       10.3.2 Indicators of a Backdraft 

Chapter 11 Extinguishment
11 Introduction 
11.1 Classes of Fire 
11.2 Interruption of the Process 
11.3 Water 
       11.3.1 Latent Heat of Vaporization 
       11.3.2 Water Flow Calculations 
11.4 Foam 
       11.4.1 Class A foam 
       11.4.2 Class B foam 
11.5 Dry Extinguishment 
11.6 Department of Transportation hazard classification system 

Chapter 12 Smoke and Products of Combustion
12 Introduction 
12.1 Characteristics of Smoke 
       12.1.1 Volume 
       12.1.2 Velocity 
       12.1.3 Density 
       12.1.4 Color 
12.2 Toxicity of Smoke 
       12.2.1 Carbon Monoxide 
       12.2.2 Hydrogen Cyanide 
12.3 Toxicity and the Untenable Environment 

Chapter 13 Fire models 
13 Introduction 
13.1 Fire Modeling Applications 
13.2 Notable NIST FDS Simulations 
13.3 Zone Models 
13.4 Computational fluid dynamics models (Field models) 

References

Michael McKenna

Michael McKenna retired after almost 32 years of professional fire service experience, including more than 19 years as a fire captain and more than seven years as a fire district safety officer. Captain McKenna is an alumnus of the International Association of Firefighters. Captain McKenna has been instructing Fire Technology, specializing in quantitative Fire Behavior, since 1999. Captain McKenna has over 21 years of fire service program management and problem-solving and solution development. He has been involved with the NFPA fire service consensus standards development since 1988 and sits as a principal member of NFPA 1950, NFPA 1851, NFPA 1930, and the Correlating Committee on Fire and Emergency Services Protective Clothing and Equipment. Captain McKenna has published many articles on firefighter issues. As a principal in Captain McKenna & Associates, LLC, he works with fire departments and other organizations on issues of firefighter safety and solutions design. He has lectured around the United States and Latin America on fire service issues, including fi re behavior. Captain McKenna is a subject matter expert on firefighter burn injuries, line-of-duty death, and near-misses and, as such, has worked as a Managing Technical Advisor to the National Institute of Occupational Safety and Health at the National Personal Protection Laboratory in Morgantown, West Virginia. In addition, Captain McKenna provides expert testimony and trial consulting in matters of firefighter injury or death. Michael McKenna has a Bachelor of Arts degree in Economics & Public Policy development from California State University Sacramento and an Associate of Arts degree in Fire Technology from American River College.

The audience for the book is primarily members of the fire service studying fire as part of a degree program, as well as anyone wanting to study fire. The intent of the book is to provide a depth of knowledge in fi re behavior, so hopefully, to provide just a bit of fire behavior information that will help firefighters make more informed decisions. It is also intended to provide enough science and extra physics, so hopefully, as the National Institute for Standards and Technology and the Fire Safety Research Institute continue to study fire, understanding the information will come more naturally to the firefighter. The book is aimed as a bridge between the oversimplistic studies of fire behavior and the full-on calculus-based, deep physics textbooks. I leave mathematical calculations intentionally out of the book but put many formulas into the book to help understand the relationships between values. I attempted to leave openings where the instructor could use the text as a launching point to go into more complicated directions if they choose. I am not a scientist but have learned the value of science and mathematics by studying fire behavior. With the exception of my time in the Safety Division, I spent my entire career riding a fire engine, putting “wet stuff on the red stuff.” The book contains many case studies because I believe it is best to intertwine real events with the study of fire behavior. Unfortunately, all the case studies have one thing in common, and that is line of duty death. Fire behavior makes every fireground a dynamic and dangerous place that can be very unpredictable. What seems completely benign can become deadly in moments. I am not talking about minutes or even seconds. Sometimes tragedy happens in an instant. Case studies provide real-life fire behavior situations. It is important to note that the event in a case study does not necessarily correspond to the chapter topic. I felt that was too limiting, and there are many important circumstances to study. These fires are presented with the mindset of fire behavior, and I made no judgments or comments on any fireground actions. The presentations are about the fire behavior. This book is not perfect, and I am always open to feedback. In the process of simplification of some of the principles, I may have lost something in the translation. Hopefully, the book leads to a better understanding of the science behind fire behavior and helps forge a better understanding of fire.

Introduction 
Preface 
Cancer 
Acknowledgements 
About the author 
Fire and Emergency Services Higher Learning (FESHE) Matrix 

Chapter 1 Introduction to Fire 
1 Introduction 
1.1 The Modern Study of Fire 
1.2 National Institute of Standards and Technology (NIST) 
1.3 UL Fire Safety Research Institute (FRSI) 
1.4 Mathematics in Fire Behavior
       1.4.1 Standard International (SI) system 
       1.4.2 Scientific Notation 
       1.4.3 Temperature Measurement 
1.5 Mathematics of Change 
       1.5.1 Inverse Relationships 
       1.5.2 Rise over Run 

Chapter 2 Science of Fire 
2  Introduction 
2.1 Fire and Combustion 
       2.1.1 The Basics of Fire 
2.2 Definition of Fire 
2.3 Heat Movement 
2.4 Fire Triangle – The Initiation of Fire 
2.5 Fire Tetrahedron 
2.6 States of Energy 
       2.6.1 Potential Energy 
       2.6.2 Kinetic Energy 
2.7 Law of Conservation of Energy 
2.8 States of Matter 
       2.8.1 Gas Molecules 
              2.8.1.1 Ideal Gas Law 
       2.8.2 Liquids 
       2.8.3 Solids 

Chapter 3 Forms of Fire 
3 Introduction 
3.1 Heat Transfer Within the Reaction Zone 
       3.1.1 Second Law of Thermodynamics 
3.2 Fuel Vapor Movement Within the Reaction Zone 
       3.2.1 Fick’s Law of Diffusion 
       3.2.2 Graham’s Law of Diffusion 
3.3 Trilogy of Energy Transfer 
3.4 Pyrolysis 
3.5 Heat of Gasification 
3.6 Fire Zone 
3.7 Forms of Fire 
       3.7.1 Diffusion Flames 
              3.7.1.1 Laminar Diffusion Flame 
              3.7.1.2 Turbulent Diffusion Flame 
       3.7.2 Smoldering 
       3.7.3 Spontaneous Combustion 
              3.7.3.1 One Meridian Plaza 
       3.7.4 Premixed Flames 
              3.7.4.1 Flash Point 
              3.7.4.2 Fire Point
              3.7.4.3 Auto-Ignition Temperature 

Chapter 4 Conduction and Convection 
4 Introduction 
4.1 Heat Versus Temperature 
4.2 Conduction 
       4.2.1 Fourier’s Law of Conduction 
       4.2.2 Specific Heat 
       4.2.3 Thermal Diffusivity 
       4.2.4 Thermal Penetration Time 
4.3 Convection  
       4.3.1 Convective Heat Transfer Coefficient 
4.4 Energy Loss 

Chapter 5 Radiation 
5 Introduction 
5.1 Radiant Heat as Driving Force 
5.2 Heat Flux 
       5.2.1 Stephan-Boltzmann Constant
5.3 Emissivity 
5.4 Radiant Heat Transfer Model
5.5 Protection from Radiant Heat

Chapter 6 Ignition 
6 Introduction 
6.1 Types of Ignitions 
6.2 Ignition of Liquids 
6.3 Ignition of Solids 
       6.3.1 Surface to Mass Ratio 
       6.3.2 Net Heat Flux 
       6.3.3 Heat Flow Through a Solid 
              6.3.3.1 Steady Flow 
              6.3.3.2 Unsteady Flow 
6.4 Fire Spread 
6.5 Flame Spread 
6.6 Flame Spread on Solid Surfaces 

Chapter 7 Heat Release Rate 
7 Introduction 
7.1 Heat Release Rate 
7.2 Traditional Heat Release Rate Curve 
7.3 Legacy Versus Modern Fire Growth Curves 
       7.3.1 Modern Fire Growth Curve 
       7.3.2 t2 Fire Growth Curves 

Chapter 8 Fire Plumes and Flow Path 
8 Introduction 
8.1 Fire Plumes 
8.2 Mathematical Shape of the Fire Plume 
8.3 Buoyancy 
8.4 Entrained Air 
       8.4.1 Flame Height 
8.5 Laminar Flow 
8.6 Ceiling Jet 
8.7 Flow Path 

Chapter 9 Compartment Fires 
9 Introduction 
9.1 Compartment Fire 
       9.1.1 Stages of a Compartment Fire 
9.2 Fire Growth Timeline 
9.3 Ventilation 
9.4 Developing Fire 
9.5 Two-Zone Model
9.6 Energy Balance 

Chapter 10 Compartment Fire Dynamics 
10 Introduction 
10.1 Rollover 
10.2 Flashover 
       10.2.1 Elements of the Flashover 
       10.2.2 Conditions Required for a Flashover 
       10.2.3 Flashover Sequence of Events 
       10.2.4 Flashover Variables 
10.3 Backdraft 
       10.3.1 Backdraft Sequence 
       10.3.2 Indicators of a Backdraft 

Chapter 11 Extinguishment
11 Introduction 
11.1 Classes of Fire 
11.2 Interruption of the Process 
11.3 Water 
       11.3.1 Latent Heat of Vaporization 
       11.3.2 Water Flow Calculations 
11.4 Foam 
       11.4.1 Class A foam 
       11.4.2 Class B foam 
11.5 Dry Extinguishment 
11.6 Department of Transportation hazard classification system 

Chapter 12 Smoke and Products of Combustion
12 Introduction 
12.1 Characteristics of Smoke 
       12.1.1 Volume 
       12.1.2 Velocity 
       12.1.3 Density 
       12.1.4 Color 
12.2 Toxicity of Smoke 
       12.2.1 Carbon Monoxide 
       12.2.2 Hydrogen Cyanide 
12.3 Toxicity and the Untenable Environment 

Chapter 13 Fire models 
13 Introduction 
13.1 Fire Modeling Applications 
13.2 Notable NIST FDS Simulations 
13.3 Zone Models 
13.4 Computational fluid dynamics models (Field models) 

References

Michael McKenna

Michael McKenna retired after almost 32 years of professional fire service experience, including more than 19 years as a fire captain and more than seven years as a fire district safety officer. Captain McKenna is an alumnus of the International Association of Firefighters. Captain McKenna has been instructing Fire Technology, specializing in quantitative Fire Behavior, since 1999. Captain McKenna has over 21 years of fire service program management and problem-solving and solution development. He has been involved with the NFPA fire service consensus standards development since 1988 and sits as a principal member of NFPA 1950, NFPA 1851, NFPA 1930, and the Correlating Committee on Fire and Emergency Services Protective Clothing and Equipment. Captain McKenna has published many articles on firefighter issues. As a principal in Captain McKenna & Associates, LLC, he works with fire departments and other organizations on issues of firefighter safety and solutions design. He has lectured around the United States and Latin America on fire service issues, including fi re behavior. Captain McKenna is a subject matter expert on firefighter burn injuries, line-of-duty death, and near-misses and, as such, has worked as a Managing Technical Advisor to the National Institute of Occupational Safety and Health at the National Personal Protection Laboratory in Morgantown, West Virginia. In addition, Captain McKenna provides expert testimony and trial consulting in matters of firefighter injury or death. Michael McKenna has a Bachelor of Arts degree in Economics & Public Policy development from California State University Sacramento and an Associate of Arts degree in Fire Technology from American River College.